Published August 28, 2013
| Version Accepted Version + Supplemental Material
Journal Article
Open
A CO-Derived Iron Dicarbyne That Releases Olefin upon Hydrogenation
Abstract
An iron diphosphineborane platform that was previously reported to facilitate a high degree of N_2 functionalization is herein shown to effect reductive CO coupling. Disilylation of an iron dicarbonyl precursor furnishes a structurally unprecedented iron dicarbyne complex. Several complexes related to this process are also characterized which allows for a comparative analysis of their respective Fe–B and Fe–C bonding. Facile hydrogenation of the iron dicarbyne at ambient temperature and 1 atm H_2 results in release of a CO-derived olefin.
Additional Information
© 2013 American Chemical Society. Received: July 5, 2013; Published: August 9, 2013. We acknowledge the NIH (GM070757) and the Beckman Institute for funding and thank Lawrence Henling for assistance with XRD studies.Attached Files
Accepted Version - nihms517270.pdf
Supplemental Material - ja406874k_si_001.pdf
Supplemental Material - ja406874k_si_002.cif
Files
ja406874k_si_001.pdf
Additional details
Identifiers
- PMCID
- PMC3794666
- Eprint ID
- 41610
- Resolver ID
- CaltechAUTHORS:20131002-111755379
Funding
- NIH
- GM070757
- Beckman Institute
Dates
- Created
-
2013-10-02Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field