CaltechAUTHORS
Published September 21, 2000 | Version Published + Supplemental Material
Journal Article Open

High-field (high-frequency) EPR spectroscopy and structural characterization of a novel manganese(III) corrole

Creators

  • 1. ROR icon California Institute of Technology
  • 2. ROR icon Technion – Israel Institute of Technology

Abstract

The X-ray structure, magnetic susceptibility, and high-field (high-frequency) EPR spectrum of manganese 5,10,15-tris(pentafluorophenyl) corrole unambiguously establish that the complex contains an isolated, slightly rhombic, manganese(III) center.

Additional Information

© 2000 The Royal Society of Chemistry. Received 02 Aug 2000, Accepted 30 Aug 2000. First published on the web 21 Sep 2000. We thank Dr M. W. Day (Beckman Institute) for assistance with the crystal structure determination and Ms S. Mossin (University of Copenhagen) and Dr A.-L. Barra (CNRS, Grenoble) for recording the HF-EPR spectra. This research was supported by the Fund for the Promotion of Research at the Technion (Z. G.), the National Science Foundation (H. B. G.), and grant # 9800549 from the Danish Natural Science Research Council (J. B.).

Attached Files

Published - BENcc00.pdf

Supplemental Material - b006299p.txt

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Additional details

Identifiers

Eprint ID
27937
Resolver ID
CaltechAUTHORS:20111123-083709397

Funding

Promotion of Research at the Technion
NSF
Danish Natural Science Research Council
9800549

Dates

Created
2011-11-23
Created from EPrint's datestamp field
Updated
2021-11-09
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