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Published August 24, 2011 | Version Supplemental Material
Journal Article Open

Iodinated Aluminum(III) Corroles with Long-Lived Triplet Excited States

Creators

  • 1. ROR icon Technion – Israel Institute of Technology
  • 2. ROR icon California Institute of Technology

Abstract

The first reported iodination of a corrole leads to selective functionalization of the four C–H bonds on one pole of the macrocycle. An aluminum(III) complex of the tetraiodinated corrole, which exhibits red fluorescence, possesses a long-lived triplet excited state.

Additional Information

© 2011 American Chemical Society. Received: April 4, 2011. Published: July 27, 2011. Publication Date (Web): July 27, 2011. This research was supported by the U.S. - Israel Binational Science Foundation (BSF) to Z.G. and H.B.G.

Attached Files

Supplemental Material - ja202692b_si_001.pdf

Supplemental Material - ja202692b_si_002.cif

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Additional details

Identifiers

Eprint ID
25460
DOI
10.1021/ja202692b
Resolver ID
CaltechAUTHORS:20110928-083924165

Funding

U.S. Israel Binational Science Foundation

Dates

Created
2011-09-28
Created from EPrint's datestamp field
Updated
2021-11-09
Created from EPrint's last_modified field