Published November 16, 2009 | Version Published
Journal Article Open

Dynamical and quasistatic structural relaxation paths in Pd_(40)Ni_(40)P_(20) glass

  • 1. ROR icon University of Göttingen
  • 2. ROR icon Arizona State University

Abstract

By sequential heat treatment of a Pd_(40)Ni_(40)P_(20) metallic glass at temperatures and durations for which α-relaxation is not possible, dynamic, and quasistatic relaxation paths below the glass transition are identified via ex situ ultrasonic measurements following each heat treatment. The dynamic relaxation paths are associated with hopping between nonequilibrium potential energy states of the glass, while the quasistatic relaxation path is associated with reversible β-relaxation events toward quasiequilibrium states. These quasiequilibrium states are identified with secondary potential energy minima that exist within the inherent energy minimum of the glass, thereby supporting the concept of the sub-basin/metabasin organization of the potential-energy landscape.

Additional Information

© 2009 American Institute of Physics. Received 28 August 2009; accepted 29 October 2009; published online 19 November 2009. Financial support is acknowledged by the DFG-SFB 602 and Sa 337/10-1 Leibniz-Program as well as the MRSEC Program of the National Science Foundation under Award No. DMR-0520565.

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Additional details

Identifiers

Eprint ID
16896
Resolver ID
CaltechAUTHORS:20091208-090858625

Funding

NSF
DMR-0520565
NSF
DFG-SFB 602
NSF
Sa 337/10-1

Dates

Created
2010-01-04
Created from EPrint's datestamp field
Updated
2021-11-08
Created from EPrint's last_modified field