CaltechAUTHORS
Published August 22, 1995 | Version Published
Journal Article Open

Rotationally resolved photoelectron spectroscopy of the [a ^1Δ]3dπ ^2Φ Rydberg state of the SH radical

Creators

  • 1. ROR icon University of Amsterdam
  • 2. ROR icon California Institute of Technology

Abstract

Results of calculated and measuredphotoelectron spectra via the [a  ^1Δ]3dπ ^2Φ state of SH are reported. These spectra show a strong asymmetry away from classical expectations and only transitions up to ΔN=±2 are observed, in contrast to ΔN=±4 expected for photoionization of a 3dπ orbital. Agreement between the calculated and measured spectra is excellent.

Additional Information

© 1995 American Institute of Physics. (Received 2 May 1995; accepted 12 June 1995) The group at the University of Amsterdam gratefully acknowledges the Netherlands Organization for Scientific Research (NWO) for equipment grants and for financial support (J.B.M.). Work at the California Institute of Technology was supported by grants from the Air Force Office of Scientific Research and the Office of Health and Environmental Research of the U.S. Department of Energy. We also acknowledge use of the resources of the Jet Propulsion Laboratory/California Institute of Technology CRAY Y-MP2E/232 supercomputer. Both groups gratefully acknowledge NATO for collaborative Grant Number CRG930183.

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Additional details

Identifiers

Eprint ID
61269
Resolver ID
CaltechAUTHORS:20151019-143013528

Funding

Nederlandse Organisatie voor Wetenschappelijk Onderzoek (NWO)
Air Force Office of Scientific Research (AFOSR)
Department of Energy (DOE)
North Atlantic Treaty Organization (NATO)
CRG930183

Dates

Created
2015-10-20
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Updated
2021-11-10
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