CaltechAUTHORS
Published April 1, 1961 | Version public
Journal Article Metadata-only

Small-Ring Compounds. XXXIII. A Study by Nuclear Magnetic Resonance of the Extent of Isotope-position Rearrangement in the Vapor-phase Photochlorination of methyl-^(13)C-Cyclopropane

Creators

Abstract

Vapor-phase photochlorination of methyl-^(13)C-cyclopropane was found to yield cyclopropylcarbinyl-α-^(13)C chloride and allyl-γ-^(13)C-carbinyl chloride. Within the experimental error of the analytical method (nuclear magnetic resonance spectroscopy), no other ^(13)C-position isomers of the chlorides were formed.

Additional Information

© 1961 American Chemical Society. Received December 14, 1960. Supported in part by the Office of Naval Research, the Petroleum Research Fund of the American Chemical Society, and the National Science Foundation. Grateful acknowledgment is hereby made to the donors of the Petroleum Research Fund. National Science Foundation Faculty Fellow, 1959-1960.

Additional details

Identifiers

Eprint ID
61324
DOI
10.1021/ja01469a049
Resolver ID
CaltechAUTHORS:20151020-105558215

Funding

Office of Naval Research (ONR)
American Chemical Society Petroleum Research Fund
NSF

Dates

Created
2015-10-20
Created from EPrint's datestamp field
Updated
2021-11-10
Created from EPrint's last_modified field

Caltech Custom Metadata

Other Numbering System Name
Caltech Gates and Crellin Laboratories of Chemistry
Other Numbering System Identifier
2646