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Published November 24, 2008 | Version Supplemental Material
Journal Article Open

Phosphido Pincer Complexes of Palladium as New Efficient Catalysts for Allylation of Aldehydes

Creators

  • 1. ROR icon University of Salerno
  • 2. ROR icon Massachusetts Institute of Technology

Abstract

Palladium complexes supported by tridentate phosphido diphosphine ligands (P(o-C6H4PR2)2: 1, R = iPr; 2, R = Ph) have been synthesized, characterized, and tested as catalysts for the electrophilic allylation of aldehydes. The palladium complex 2 resulted in an interesting catalyst for electrophilic allylation in the presence of allyltributyltin, giving good yields under very mild reaction conditions and even in the absence of the solvent.

Additional Information

Copyright © 2008 American Chemical Society. Received September 3, 2008. Publication Date (Web): October 22, 2008. We thank Matt T. Whited for assistance with crystallographic studies. Supporting Information: Text, figures, and tables giving experimental procedures for the synthesis and characterization data of compounds 1 and 2 and X-ray structural solution and crystal data for 1; X-ray data for 1 are also given as a CIF file. This material is available free of charge via the Internet at http://pubs.acs.org.

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Supplemental Material - MAZo08supp.pdf

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Additional details

Identifiers

Eprint ID
12675
Resolver ID
CaltechAUTHORS:MAZo08

Dates

Created
2008-12-19
Created from EPrint's datestamp field
Updated
2021-11-08
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