Published August 15, 2017
| Version public
Journal Article
Electronic structures and photophysics of d^8-d^8 complexes
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1.
California Institute of Technology
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2.
J. Heyrovsky Institute of Physical Chemistry
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3.
Queen Mary University of London
Abstract
Research on d^8-d^8 complexes is being actively pursued, owing, in part, to newly developed time-resolved optical, IR, and X-ray methods that directly interrogate bonding changes upon excitation. Our review covers work on the ground- and electronic excited states, as well as the oxidized and reduced forms, of these complexes. Recent experimental and theoretical results add a new chapter to the rich history of d^8-d^8 spectroscopic and chemical behavior.
Additional Information
© 2017 Elsevier B.V. Received 29 October 2016, Revised 17 January 2017, Accepted 18 January 2017, Available online 21 January 2017. We thank our colleagues for interesting discussions of d^8-d^8 chemistry as well as sharing some (yet) unpublished data, most especially Majed Chergui, Ivano Tavernelli, Roberto Moni, and Gloria Capano (EFPFL, Switzerland); and Jay Winkler, Bryan Hunter, and Yan-Choi Lam (Caltech). This work was supported by the NSF CCI Solar Fuels Program (CHE-1305124), the Arnold and Mabel Beckman Foundation, the Ministry of Education of the Czech Republic - grant LH13015, and the COST Action CM1405. Dedicated to Barry Lever, consummate scholar and treasured friend, in recognition of his deep and lasting contributions to coordination chemistry.Additional details
Identifiers
- Eprint ID
- 74420
- DOI
- 10.1016/j.ccr.2017.01.008
- Resolver ID
- CaltechAUTHORS:20170221-084923487
Funding
- NSF
- CHE-1305124
- Arnold and Mabel Beckman Foundation
- Ministry of Education (Czech Republic)
- LH13015
- COST Action
- CM1405
Dates
- Created
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2017-02-21Created from EPrint's datestamp field
- Updated
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2021-11-11Created from EPrint's last_modified field
Caltech Custom Metadata
- Caltech groups
- CCI Solar Fuels