Published August 2016
| Version public
Conference Paper
Z-selective cross metathesis with 3(E)-1,3-dienes
Abstract
A method for olefin metathesis between 3(E)-1,3-dienes and terminal olefins is described. The method employs a recently reported ruthenium-based catalyst contg. a cyclometalated NHC ligand and takes advantage of its pronounced selectivity for terminal olefins in the presence of internal E-olefins. A wide variety of functional groups can be tolerated. Applications of the reaction include direct synthesis of insect pheromones from commerical precursor.
Additional Information
© 2016 American Chemical Society.Additional details
Identifiers
- Eprint ID
- 70312
- Resolver ID
- CaltechAUTHORS:20160913-123515387
Related works
- Describes
- https://www.acs.org/content/acs/en/meetings/fall-2016.html (URL)
Dates
- Created
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2016-09-30Created from EPrint's datestamp field
- Updated
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2019-10-03Created from EPrint's last_modified field