Published March 2014 | Version public
Journal Article

Intra- and intermolecular electron hopping via tryptophan in azurin

Abstract

We previously showed that electron transfer (ET) between electronically excited Re (^*RE) and Cu(I)in Re-modified Pseudomonas aeruginosa azurin mutant ReH124W122Cu(I)(Re=4,7-dimethylphenanthrolineRe(CO)3) is facilitated by W122, with hopping occurring over 19 Å in 30 ns, >100x faster than single step electron tunneling.

Additional Information

© 2014 Springer. CONTROL ID: 1709659

Additional details

Identifiers

Eprint ID
45200
DOI
10.1007/s00775-014-1095-8
Resolver ID
CaltechAUTHORS:20140424-153153082

Dates

Created
2014-04-24
Created from EPrint's datestamp field
Updated
2021-11-10
Created from EPrint's last_modified field