CaltechAUTHORS
Published January 29, 1997 | Version public
Journal Article Metadata-only

Reversible Nitrogen Atom Transfer between Nitridomanganese(V) and Manganese(III) Schiff-Base Complexes

Creators

  • 1. ROR icon California Institute of Technology

Abstract

Nitrogen atom transfer from salen-derived nitridomanganese(V) to manganese(III) Schiff-base complexes occurs under aerobic conditions in solution at room temperature. A mechanism involving chloride dissociation followed by the formation and decay of a binuclear μ-nitrido-activated complex accounts satisfactorily for the observed kinetics data.

Additional Information

© 1997 American Chemical Society. Received August 22, 1996. We thank John Bercaw, Justin DuBois, and Jay Winkler for helpful discussions and Fred Anson for the loan of a thermostatable cell holder. C.J.C. participated in the Summer Undergraduate Research Fellowship (SURF) program at Caltech during 1995 and 1996. D.W.L. acknowledges a fellowship from the Parsons Foundation. This work was supported by the NSF.

Additional details

Identifiers

Eprint ID
86666
Resolver ID
CaltechAUTHORS:20180529-113212317

Funding

Caltech Summer Undergraduate Research Fellowship (SURF)
Ralph M. Parsons Foundation
NSF

Dates

Created
2018-05-29
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Updated
2021-11-15
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