Published January 15, 1993
| Version Published
Journal Article
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Structure of a syn-aldol addition product of benzaldehyde and a prolinol-derived O-silacyclopentyl ketene N,O-acetal
Abstract
The compound (5S,6S,11aS)-hexahydro-6-methyl-5- phenylspiro[l H,7 H-pyrrolo[2,l-e][l,3,6,2]dioxazasilonine- 3,1'-silacyclopentan]-7-one (1) results from the silicon-directed condensation of the prolinol-derived O-silacyclopentyl ketene N,O-acetal (2) with benzaldehyde. The five-membered pyrrolidine ring has an envelope conformation and the silacyclopentyl ring has an en-type conformation with C17 and C18 on opposite sides of the C16-Si-C19 plane. Both of these rings appear to be disordered.
Additional Information
© 1993 International Union of Crystallography. Received 13 May 1992; accepted 14 August 1992. Financial support from the National Science Foundation is gratefully acknowledged. SEK acknowledges an NSF predoctoral fellowship.Attached Files
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Identifiers
- Eprint ID
- 73585
- Resolver ID
- CaltechAUTHORS:20170120-131546321
Funding
- NSF Predoctoral Fellowship
Dates
- Created
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2017-01-21Created from EPrint's datestamp field
- Updated
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2021-11-11Created from EPrint's last_modified field
Caltech Custom Metadata
- Other Numbering System Name
- Caltech Division of Chemistry and Chemical Engineering
- Other Numbering System Identifier
- 8633