Published December 22, 2008
| Version Supplemental Material + Accepted Version
Journal Article
Open
Catalytic Asymmetric Cross-Couplings of Racemic α-Bromoketones with Arylzinc Reagents
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1.
Massachusetts Institute of Technology
Abstract
Nickel box : The first catalytic asymmetric method for cross‐coupling arylzinc reagents with α‐bromoketones has been developed (see scheme). This stereoconvergent carbon–carbon bond‐forming process occurs under unusually mild conditions and without activators, thereby allowing the generation of potentially labile tertiary stereocenters.
Additional Information
© 2009 WILEY‐VCH. Received: October 6, 2008. Published online: November 28, 2008. Support has been provided by the National Institutes of Health (National Institute of General Medical Sciences, grant R01‐GM62871), Merck Research Laboratories, Novartis, and the Spanish Department of Science (fellowship for J.E.).Attached Files
Accepted Version - nihms100112.pdf
Supplemental Material - anie_200804888_sm_miscellaneous_information.pdf
Files
anie_200804888_sm_miscellaneous_information.pdf
Additional details
Identifiers
- PMCID
- PMC2790061
- Eprint ID
- 104087
- DOI
- 10.1002/anie.200804888
- Resolver ID
- CaltechAUTHORS:20200626-123754710
Related works
- Describes
- 10.1002/anie.200804888 (DOI)
Funding
- NIH
- R01‐GM62871
- Merck Research Laboratories
- Novartis
- Ministerio de Ciencia e Innovación (MCINN)
Dates
- Created
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2020-06-26Created from EPrint's datestamp field
- Updated
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2021-11-16Created from EPrint's last_modified field