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Published April 29, 2002 | Version Supplemental Material
Journal Article Open

Base-Promoted Benzene C−H Activation Chemistry at an Amido Pincer Complex of Platinum(II)

Creators

  • 1. ROR icon California Institute of Technology

Abstract

The thermally robust platinum(II) complex (BQA)Pt(OTf) undergoes benzene C−H bond activation at 150 °C but requires the presence of N^iPr_2Et. The reaction products are the phenyl complex (BQA)Pt(Ph) and a stoichiometric equivalent of [HN^iPr_2Et][OTf].

Additional Information

© 2002 American Chemical Society. Received December 7, 2001; Publication on Web 04/02/2002. We thank BP, Caltech, and the Dreyfus Foundation for financial support of this work and Larry Henling for crystallographic assistance. Members of the Bercaw group are thanked for insightful discussions.

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Identifiers

Eprint ID
47399
Resolver ID
CaltechAUTHORS:20140722-122514070

Funding

BP
Caltech
Camille and Henry Dreyfus Foundation

Dates

Created
2014-07-22
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Updated
2021-11-10
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