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Published November 28, 2009 | Version Supplemental Material + Published
Journal Article Open

Redox rich dicobalt macrocycles as templates for multi-electron transformations

Creators

  • 1. ROR icon Massachusetts Institute of Technology

Abstract

Pyridazine-templated dicobalt macrocycles reversibly support five oxidation states with unusually positive Co^(II)/Co^I redox couples, and are also active proton reduction electrocatalysts.

Additional Information

This journal is © The Royal Society of Chemistry 2009. Received 13 Jul 2009, Accepted 17 Sep 2009, First published online 06 Oct 2009. This work was generously supported by BP and an NSF Center for Chemical Innovation grant (Grant CHE-0802907). We thank Dr Yunho Lee and Dr Sebastian Stoian for EPR assistance, and Dr Bruce Brunschwig for helpful discussions. Electronic supplementary information (ESI) available: Complete experimental details and crystal structures. CCDC 740044–740052. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b913946j

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Published - b913946j.pdf

Supplemental Material - b913946j__1_.pdf

Supplemental Material - b913946j.txt

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Additional details

Identifiers

Eprint ID
44646
Resolver ID
CaltechAUTHORS:20140403-151953405

Funding

BP
NSF Center for Chemical Innovation
CHE-0802907

Dates

Created
2014-04-03
Created from EPrint's datestamp field
Updated
2021-11-10
Created from EPrint's last_modified field

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