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Published March 20, 2003 | Version Supplemental Material
Journal Article Open

Palladium-Catalyzed Enantioselective Oxidation of Alcohols: A Dramatic Rate Acceleration by Cs_2CO_3/t-BuOH

Creators

  • 1. ROR icon California Institute of Technology

Abstract

The addition of Cs_2CO_3 and t-BuOH provides a dramatic rate acceleration in the palladium-catalyzed aerobic oxidative kinetic resolution of secondary alcohols while maintaining the selectivity of the process.

Additional Information

© 2003 American Chemical Society. Received 13 December 2002. Published online 14 February 2003. Published in print 1 March 2003. We wish to thank the NIH-NIGMS (R01 GM65961-01), the California Institute of Technology, the Camille and Henry Dreyfus Foundation (New Faculty Award to B.M.S.), the Merck Research Laboratories, Research Corporation, The University of California TRDRP (predoctoral fellowship to J.T.B.), the National Science Foundation (predoctoral fellowship to E.M.F.), GlaxoSmithKline, and Abbott Laboratories for generous financial support.

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Supplemental Material - ol027463psi20030203_123157.pdf

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Additional details

Identifiers

Eprint ID
74472
Resolver ID
CaltechAUTHORS:20170222-145100100

Funding

NIH
R01GM65961-01
Caltech
Camille and Henry Dreyfus Foundation
Merck Research Laboratories
Research Corporation
California Tobacco-Related Disease Research Program
NSF Predoctoral Fellowship
GlaxoSmithKline
Abbott Laboratories

Dates

Created
2017-02-22
Created from EPrint's datestamp field
Updated
2021-11-11
Created from EPrint's last_modified field