Published February 25, 2011
| Version Accepted Version
Journal Article
Open
Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand
Abstract
Adaptable metallaboratranes: A tris- (phosphino)borane ligand stabilizes both low-valent Fe-N_2 complexes and a mid-valent imido species with a Fe≡NAr bond, thanks to its ability to shuttle between trigonal-bipyramidal and pseudotetrahedral geometries by elongation of the apical iron–boron bond (see picture)
Additional Information
© 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: November 4, 2010. Article first published online: 26 January 2011. This work was supported by the NIH (GM 070757). M.-E.M. acknowledges a Fellowship for Prospective Researchers from the Swiss National Science Foundation. We thank Charlene Tsay and Larry Henling for crystallographic assistance, as well as David VanderVelde for assistance with DOSY experiments and Angelo Di Bilio for EPR measurements.Attached Files
Accepted Version - nihms413316.pdf
Files
nihms413316.pdf
Additional details
Identifiers
- PMCID
- PMC4165522
- Eprint ID
- 23163
- Resolver ID
- CaltechAUTHORS:20110329-153028868
Funding
- NIH
- GM 070757
- Swiss National Science Foundation
Dates
- Created
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2011-04-01Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field