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Published January 1962 | Version public
Journal Article Metadata-only

Small-Ring Compounds. XXXVII. Free Radical Decarbonylation of Some Cyclopropanecarboxaldehydes

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Abstract

The di-t-butyl peroxide initiated decarbonylations of cyclopropanecarboxaldehyde and 1-methyl- and 1-phenylcyclopropanecarboxaldehyde have been studied. The first of these did not undergo decerbonylation to a measurable extent, while the substituted aldehydes reacted without ring opening to give methyl- and phenylcyclopropane, respectively.

Additional Information

© 1962 American Chemical Society. Received August 2, 1961. Supported in part by the Petroleum Research Fund of the American Chemical Society and the National Science Foundation. Grateful acknowledgment is hereby made to the Donors of the Petroleum Research Fund. National Science Foundation Predoctoral Fellow 1956-1960.

Additional details

Identifiers

Eprint ID
61221
Resolver ID
CaltechAUTHORS:20151016-143424455

Funding

American Chemical Society Petroleum Research Fund
NSF
NSF Predoctoral Fellowship

Dates

Created
2015-10-16
Created from EPrint's datestamp field
Updated
2021-11-10
Created from EPrint's last_modified field

Caltech Custom Metadata

Other Numbering System Name
Caltech Gates and Crellin Laboratories of Chemistry
Other Numbering System Identifier
2735