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Published April 1993 | Version Published
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A diphenylformamidinate-bridged terpyridineplatinum(II) dimer

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Abstract

The compound μ-N,N' -diphenylformamidinatobis[ 2,2',2"-terpyridineplatinum(II)] perchlorate mono hydrate (1) is formed by reaction of diphenylformamidine and [Pt(tpy)Cl]Cl (tpy = terpyridine) in the presence of excess base. The two platinum centers are bridged by a single diphenylformamidinato ligand with the remaining coordination geometry completed by the terpyridine group. The platinum-platinum separation is 3.049 (1) Å.

Additional Information

© 1993 International Union of Crystallography. Received 3 June 1992; accepted 29 September 1992. We thank William Schaefer for assistance. This work was supported by an NSERC (Canada) Postdoctoral Fellowship to JAB and a grant from the Office of Naval Research.

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Eprint ID
70343
Resolver ID
CaltechAUTHORS:20160914-102216766

Funding

Natural Sciences and Engineering Research Council of Canada (NSERC)
Office of Naval Research (ONR)

Dates

Created
2016-09-29
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Updated
2021-11-11
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