Published June 15, 1996 | Version Published
Journal Article Open

Molecular photoionization as a probe of vibrational–rotational–electronic correlations

  • 1. ROR icon Louisiana State University
  • 2. ROR icon California Institute of Technology

Abstract

We determine the rotationally state‐resolved 2σ_u^(−1) photoionization of N_2 into alternative vibrational channels as a function of energy over a 200 eV range. Experiment and theory reveal that Cooper minima highlight the coupling between electronic, vibrational, and rotational degrees of freedom over this very wide range.

Additional Information

© 1996 American Institute of Physics. (Received 18 March 1996; accepted 12 April 1996) We thank the CAMD staff for their assistance. E. D. P. acknowledges support from NSF (CHE-9315857). Work at Caltech was supported by the Air Force Office of Scientific Research, the Office of Health and Environmental Research of the U.S. Department of Energy, and the JPL/Caltech CRAY Y-MP2E/232 Supercomputer.

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Identifiers

Eprint ID
61267
Resolver ID
CaltechAUTHORS:20151019-143012973

Funding

NSF
CHE-9315857
Air Force Office of Scientific Research (AFOSR)
Department of Energy (DOE)

Dates

Created
2015-10-20
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Updated
2021-11-10
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