CaltechAUTHORS
Published June 1, 2001 | Version public
Journal Article Metadata-only

High-Valent Manganese Corroles and the First Perhalogenated Metallocorrole Catalyst

Creators

  • 1. ROR icon Technion – Israel Institute of Technology
  • 2. ROR icon California Institute of Technology
  • 3. ROR icon Tel Aviv University

Abstract

On pyrrole! The pyrrole-based corrole ligands can offer an alternative to porphyrin systems. The manganese corroles 1–4 are readily synthesized, undergo metal- not ligand-based redox chemistry, and 4 in particular shows impressive catalytic activity in the oxygenation of styrene with iodosylbenzene.

Additional Information

© 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany. Issue online: 28 May 2001. Version of Record online: 28 May 2001. Manuscript Received: 17 Jan 2001. This research (No. 368/00) was supported by the Israel Science Foundation (Z.G.), the US National Science Foundation (H.B.G.), and the Fund for the Promotion of Research at the Technion (Z.G.).

Additional details

Identifiers

Eprint ID
77928
Resolver ID
CaltechAUTHORS:20170602-151432131

Funding

Israel Science Foundation
368/00
NSF
Technion

Dates

Created
2017-06-03
Created from EPrint's datestamp field
Updated
2021-11-15
Created from EPrint's last_modified field