CaltechAUTHORS
Published June 1, 2010 | Version public
Journal Article Metadata-only

Access to Well-Defined Ruthenium(I) and Osmium(I) Metalloradicals

Creators

  • 1. ROR icon Massachusetts Institute of Technology
  • 2. ROR icon California Institute of Technology

Abstract

Radically complex: Well-defined mononuclear RuI and OsI complexes (see scheme) have metalloradical character, as indicated by EPR spectroscopy and DFT calculations. The Ru^I and Os^I metalloradicals exhibit both one-electron and two-electron redox reactivity. The latter process affords unusual imido complexes with substantial radical character on the {ArN} moiety.

Additional Information

© 2010 Wiley. Received: 26 February 2010; Published online: May 7, 2010. This work was supported by the NIH (GM070757). Samantha MacMillan and Dr. Peter Mller are acknowledged for crystallographic assistance. The NSF is acknowledged for use of instruments at the MIT DCIF (CHE-9808061, DBI-97299592).

Additional details

Identifiers

Eprint ID
18957
DOI
10.1002/anie.201001199
Resolver ID
CaltechAUTHORS:20100709-101044545

Related works

Describes
10.1002/anie.201001199 (DOI)

Funding

NIH
GM070757
NSF
CHE-9808061
NSF
DBI-97299592

Dates

Created
2010-07-09
Created from EPrint's datestamp field
Updated
2021-11-08
Created from EPrint's last_modified field