CaltechAUTHORS
Published May 1, 1960 | Version public
Journal Article Metadata-only

Small-Ring Compounds. XXVIII. Isotope-Position Rearrangements of Allylcarbinyl Grignard Reagents

Creators

Abstract

We have observed a remarkable rearrangement while attempting to prepare 4-penten-2-ylarnine (I) through the reaction of the Grignard reagent derived from 4-penten-2-yl chloride (II) with methoxylamine, in that part of the amine formed appeared to be 2-methyl-3-butenylamine (III).

Additional Information

© 1960 American Chemical Society. Received April 9, 1960. Supported in part by the Office of Naval Research and the Petroleum Research Fund of the American Chemical Society. Grateful acknowledgment is hereby made to the donors of the Petroleum Research Fund. Presented in part at the Sixteenth National Organic Symposium, Seattle, Washington, June 15, 1959.

Additional details

Identifiers

Eprint ID
61335
DOI
10.1021/ja01495a068
Resolver ID
CaltechAUTHORS:20151020-124117005

Funding

Office of Naval Research (ONR)
American Chemical Society Petroleum Research Fund

Dates

Created
2015-10-20
Created from EPrint's datestamp field
Updated
2021-11-10
Created from EPrint's last_modified field

Caltech Custom Metadata

Other Numbering System Name
Caltech Gates and Crellin Laboratories of Chemistry
Other Numbering System Identifier
2570