CaltechAUTHORS
Published July 28, 2010 | Version Supplemental Material
Journal Article Open

Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation

Creators

  • 1. ROR icon Korea University
  • 2. ROR icon Korea Institute of Science and Technology
  • 3. ROR icon Jagiellonian University
  • 4. ROR icon California Institute of Technology

Abstract

Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H_2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.

Additional Information

© 2010 American Chemical Society. Received February 27, 2010. Publication Date (Web): July 2, 2010. This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science, and Technology (2010-0018456). This research was performed in collaboration with the Hydrogen Energy R&D Center, which is funded by the 21st Century Frontier R&D Program of MEST.

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Additional details

Identifiers

Eprint ID
19490
DOI
10.1021/ja101685u
Resolver ID
CaltechAUTHORS:20100818-095527649

Related works

Describes
10.1021/ja101685u (DOI)

Funding

Ministry of Education, Science, and Technology (Korea)
2010-0018456

Dates

Created
2010-08-18
Created from EPrint's datestamp field
Updated
2021-11-08
Created from EPrint's last_modified field