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Published September 24, 1997 | Version Supplemental Material
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Electroreduction of O_2 to H_2O at Unusually Positive Potentials Catalyzed by the Simplest of the Cobalt Porphyrins

Creators

  • 1. ROR icon California Institute of Technology

Abstract

Simple cobalt porphine, adsorbed on graphite electrodes, catalyzes the direct reduction of O_2 to H_2O, while most other monomeric cobalt porphyrins do not. The surprising behavior of cobalt porphine suggests possible new strategies for the design of electrocatalysts for the reduction of O_2 to H_2O using structurally similar but more oxidation-resistant analogs.

Additional Information

© 1997 American Chemical Society. Received May 1, 1997. Publication Date (Web): September 24, 1997. This work was supported by the National Science Foundation.

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Additional titles

Alternative title
Electroreduction of O2 to H2O at Unusually Positive Potentials Catalyzed by the Simplest of the Cobalt Porphyrins

Identifiers

Eprint ID
86565
Resolver ID
CaltechAUTHORS:20180523-110226758

Funding

NSF

Dates

Created
2018-05-24
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Updated
2021-11-15
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