CaltechAUTHORS
Published August 1, 1962 | Version public
Journal Article Metadata-only

Nuclear Magnetic Resonance Spectroscopy. Long-Range H-F Spin-Spin Coupling in 1,1-Difluoro-2,2-dichloro-3-phenyl-3-methylcyclobutane

Creators

Abstract

A 2 C.P.S. long-range H-F spin-spin coupling has been observed over fire saturated bonds in 1,1-difluoro-2,2-dichloro-3-phenyl-3-metliylcyclobutane, involving one of the fluorines at the 1-position and the protons of the 3-methyl group. Comparison of the spectrum with that of stereospecifically labeled 4-deuterio derivatives suggests that the fluorine involved in the long-range coupling is the one cis to the methyl group.

Additional Information

© 1962 American Chemical Society. Received March 7, 1962. Supported in part by the Kureha Chemical Ind. Co. (Japan) and the Office of Naval Research.

Additional details

Identifiers

Eprint ID
61298
DOI
10.1021/ja00874a018
Resolver ID
CaltechAUTHORS:20151020-073602006

Funding

Kureha Chemical Ind. Co.
Office of Naval Research (ONR)

Dates

Created
2015-10-20
Created from EPrint's datestamp field
Updated
2021-11-10
Created from EPrint's last_modified field

Caltech Custom Metadata

Other Numbering System Name
Caltech Gates and Crellin Laboratories of Chemistry
Other Numbering System Identifier
2866