Published February 11, 2011
| Version Supplemental Material
Journal Article
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Trinucleating Copper: Synthesis and Magnetostructural Characterization of Complexes Supported by a Hexapyridyl 1,3,5-Triarylbenzene Ligand
Abstract
Copper threesome: A hexapyridyl ligand based upon a 1,3,5-triphenylbenzene framework coordinates three metal centers in a constrained environment (see picture). The tricopper(I) complex reduces dioxygen to form a tricopper(II) cluster. The capping anions affect the magnetism and EPR spectra of these species and reveal a linear dependence between the antiferromagnetic exchange parameter and the Cu-O-Cu angles.
Additional Information
© 2011 Wiley. Received: August 21, 2010. Revised: October 24, 2010. Published online: January 11, 2011. We thank Lawrence M. Henling for crystallographic assistance, David Vandervelde for help with NMR experiments, and Harry Gray, Jay Winkler and Liviu Mirica for stimulating discussions. We are grateful to Caltech and NSF GRFP (E.Y.T.) for funding. The Bruker KAPPA APEXII X-ray diffractometer was purchased through an NSF CRIF:MU award to Caltech, CHE-0639094. SQUID data were collected at the MMRC of the Beckman Institute of the California Institute of Technology.Attached Files
Supplemental Material - anie_201005232_sm_miscellaneous_information.pdf
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anie_201005232_sm_miscellaneous_information.pdf
Additional details
Identifiers
- Eprint ID
- 22921
- DOI
- 10.1002/anie.201005232
- Resolver ID
- CaltechAUTHORS:20110316-093011185
Related works
- Describes
- 10.1002/anie.201005232 (DOI)
Funding
- Caltech
- NSF Graduate Research Fellowship
- NSF
- CHE-0639094
Dates
- Created
-
2011-03-16Created from EPrint's datestamp field
- Updated
-
2021-11-09Created from EPrint's last_modified field