CaltechAUTHORS
Published March 1972 | Version public
Journal Article Metadata-only

Nuclear Magnetic Resonance Spectroscopy. Ring Inversion in 1,1 -Difluorocyclodecane

Creators

Abstract

Rates of ring inversion of 1,1-difluorocyclodecane were obtained from line-shape changes in the low-temperature ^(19)F nmr spectra. At -135º, the free energy of activation was 5.7 kcal/mol. The results are interpreted in terms of a boat-chair-boat conformation. Possible pathways for effecting ring inversion are discussed.

Additional Information

© 1972 American Chemical Society. Received July 1, 1971. Supported by the National Science Foundation. Summer National Science Foundation Fellow, 1966 and 1968; National Defense Education Act Trainee, 1968-1969.

Additional details

Identifiers

Eprint ID
60959
Resolver ID
CaltechAUTHORS:20151009-133527182

Funding

NSF
Summer National Science Foundation Fellow
National Defense Education Act Trainee

Dates

Created
2015-10-15
Created from EPrint's datestamp field
Updated
2021-11-10
Created from EPrint's last_modified field

Caltech Custom Metadata

Other Numbering System Name
Caltech Gates and Crellin Laboratories of Chemistry
Other Numbering System Identifier
4275