CaltechAUTHORS
Published October 24, 1986 | Version public
Journal Article Metadata-only

Real-time measurements of IVR versus inferences from spectral broadening data: the alkylanilines "ring + tail" system

Creators

  • 1. ROR icon California Institute of Technology

Abstract

We report on picosecond/molecular beam studies of alkylanilines. The studies reveal important discrepancies between real-time measurements and inferences from spectral broadening data. We observe quantum recurrences and we find that the observed severe spectral congestion does not correspond to the observed coherence. The effect of mode symmetry and energy on IVR dynamics is also examined.

Additional Information

© 1986 Elsevier B.V. Received 19 August 1986, in final form 27 August 1986. This work is supported by the National Science Foundation under Grant CHE-8512887. We wish to thank the group of Professor W.A. Goddard III for helping us to produce fig. 1 and Professor R.B. Bernstein for very helpful suggestions.

Additional details

Identifiers

Eprint ID
70458
Resolver ID
CaltechAUTHORS:20160920-093337135

Funding

NSF
CHE-8512887

Dates

Created
2016-09-29
Created from EPrint's datestamp field
Updated
2021-11-11
Created from EPrint's last_modified field

Caltech Custom Metadata

Other Numbering System Name
Arthur Amos Noyes Laboratory of Chemical Physics
Other Numbering System Identifier
7458