Published December 6, 2006
| Version Supplemental Material
Journal Article
Open
Template-Directed One-Step Synthesis of Cyclic Trimers by ADMET
Creators
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1.
California Institute of Technology
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2.
University of California, Los Angeles
Abstract
A trifurcated template, containing three secondary dialkylammonium ion recognition sites for encirclement by a dibenzo [24]crown-8-containing acyclic diene, is used to promote acyclic diene metatheses (ADMET) catalyzed by ruthenium−alkylidene complexes, affording a cyclic trimer in 55% yield. Following this one-step, threefold ADMET reaction, the resulting cyclic trimer was isolated by preparative HPLC and characterized by NMR spectroscopy and mass spectrometry.
Additional Information
© 2006 American Chemical Society. Received August 1, 2006. Publication Date (Web): November 9, 2006. We thank the office of Naval Research (ONR) for supporting this research through the Multidisciplinary University Research Initiative (MURI) program.Attached Files
Supplemental Material - ja065572jsi20061013_112041.pdf
Files
ja065572jsi20061013_112041.pdf
Additional details
Identifiers
- Eprint ID
- 76760
- Resolver ID
- CaltechAUTHORS:20170420-105532746
Funding
- Office of Naval Research (ONR)
Dates
- Created
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2017-04-20Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field