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Published February 1, 1966 | Version Published
Journal Article Open

Nitrogen-15 Magnetic Resonance Spectroscopy. VII. Chemical Shifts of para-Substituted Nitrobenzenes

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Abstract

The ^(15)N chemical shifts of a series of para-substituted nitrobenzenes have been measured. Comparison with the para-^(13)C chemical shifts in monosubstituted benzenes and with ^(19)F chemical shifts in para-substituted fluorobenzenes, indicates that similar factors determine the chemical shifts of these three nuclei. With p-nitroaniline, the ^(15)N chemical shift appears to have an extra paramagnetic contribution, since this is the only compound studied that does not fit the correlation with ^(13)C and ^(19)F chemical shifts.

Additional Information

© 1966 American Chemical Society. Received September 30, 1965. Supported in part by the Public Health Service Research Grant 11072-02 from the Division of General Medical Sciences and the National Science Foundation.

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Eprint ID
61125
Resolver ID
CaltechAUTHORS:20151014-144944278

Funding

U.S. Public Health Service (USPHS)
11072-04
NSF

Dates

Created
2015-10-15
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Updated
2021-11-10
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Other Numbering System Name
Caltech Gates and Crellin Laboratories of Chemistry
Other Numbering System Identifier
3308