Published August 24, 2010 | Version Supplemental Material
Journal Article Open

Pushing the Limits for Thiol−Ene and CuAAC Reactions: Synthesis of a 6th Generation Dendrimer in a Single Day

  • 1. ROR icon Royal Institute of Technology
  • 2. ROR icon University of California, Santa Barbara

Abstract

Dendrimer synthesis should not be tedious and time-consuming. By utilizing an AB2−CD2 approach and having orthogonal, "clickable" groups on each monomer, the time for dendrimer assembly can be drastically reduced. This was shown by preparation of a sixth generation dendrimer from starting monomer units in a single day.

Additional Information

© 2010 American Chemical Society. Received June 3, 2010; Revised Manuscript Received July 7, 2010. Financial support from the NSF (CHE-0957492, the MRSEC Program DMR-0520415 (MRL-UCSB)), UC Regents for a President's Fellowship (L.M.C.) and Graduate Fellowship (M.J.R.), the Swedish Research Council (M.M.) (Grant 2006-3617), Bengt Lundqvists Minnesfond (P.A.), and Instituto de Salud Carlos III (M.I.M.) is greatly acknowledged.

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Additional details

Identifiers

Eprint ID
86818
DOI
10.1021/ma101242u
Resolver ID
CaltechAUTHORS:20180605-164810729

Related works

Describes
10.1021/ma101242u (DOI)

Funding

NSF
CHE-0957492
NSF
DMR-0520415
UC Regents
Swedish Research Council
2006-3617
Bengt Lundqvists Minnesfond
Instituto de Salud Carlos III

Dates

Created
2018-06-06
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Updated
2021-11-15
Created from EPrint's last_modified field