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Published September 28, 2014 | Version Published + Supplemental Material
Journal Article Open

A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M–R to vanadate oxo

Creators

  • 1. ROR icon California Institute of Technology

Abstract

A new mechanism for generating C–O bonds from metal-hydrocarbyls involving homolytic, intermolecular migration of the hydrocarbyl group to a vanadium oxo is reported. Responsible for the C–O bond in phenol formed by the reaction of OVCl_3 with HgPh_2, it may provide air-regenerable metal oxos a role in aerobic alkane oxidations.

Additional Information

© 2014 The Royal Society of Chemistry. Received 24 Apr 2014, Accepted 28 Jul 2014, First published online 28 Jul 2014. This work was initiated with support from the Center for Catalytic Hydrocarbon Functionalization, an Energy Frontier Research Center, DOE DE-SC0001298, and completed with support from Chevron USA INC and from NSF (CHE-1214158).

Attached Files

Published - c4cc03067b.pdf

Supplemental Material - c4cc03067b1_si.pdf

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Additional details

Identifiers

Eprint ID
48221
Resolver ID
CaltechAUTHORS:20140808-083238459

Funding

Department of Energy (DOE)
DE-SC0001298
Chevron USA Inc.
NSF
CHE-1214158

Dates

Created
2014-08-08
Created from EPrint's datestamp field
Updated
2023-06-07
Created from EPrint's last_modified field

Caltech Custom Metadata

Other Numbering System Name
WAG
Other Numbering System Identifier
1055