Published March 3, 1989
| Version public
Journal Article
Picosecond studies of jet-cooled chromyl chloride
Abstract
The dynamics of the ^1B_1 state of chromyl chloride, CrO_2Cl_2, are investigated via picosecond time-resolved measurements on a jet-cooled sample. Quasi-biexponential time evolution of fluorescence is observed for each of the nine single vibronic levels studied. A rapid, mode-dependent acceleration of the decay rates with excess vibrational energy is reported. The time dependence is described by a kinetic model and the non-radiative decay channels which may be responsible for the observed behavior are discussed.
Additional Information
© 1989 Elsevier Science Publishers B.V. Received 1 November 1988; in final form 9 December 1988. This research was supported by the Caltech Consortium in Chemistry and Chemical Engineering; founding members: E.I. du Pont de Nemours and Company, Inc., Eastman Kodak Company, Minnesota Mining and Manufacturing Company, and Shell Oil Company Foundation. We wish to thank the referee for useful comments.Additional details
Identifiers
- Eprint ID
- 70151
- Resolver ID
- CaltechAUTHORS:20160902-105851543
Funding
- Caltech Consortium in Chemistry and Chemical Engineering
- E. I. DuPont de Nemours and Company, Inc.
- Eastman Kodak Company
- Minnesota Mining and Manufacturing Company
- Shell Oil Company Foundation
Dates
- Created
-
2016-09-02Created from EPrint's datestamp field
- Updated
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2021-11-11Created from EPrint's last_modified field
Caltech Custom Metadata
- Other Numbering System Name
- Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 7880